Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties.
نویسندگان
چکیده
A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In contrast to previous studies, this compound shows considerable π-donor properties as the result of the rather strong +M effect of the CH3S-substituent, changing the electronic properties of this low-coordinate and aromatic phosphorus heterocycle substantially.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 64 شماره
صفحات -
تاریخ انتشار 2014